The stunning couple were seen fawning over British rapper Tinie Tempah on Sunday at a BAFTAs after party in London.
Pressing the 25-year-old between them, Brangelina looked eager to pose for a memento with the hip hop artist.
Fans: Angelina Jolie and Brad Pitt posed for a photo with Tinie Tempah at the BAFTA after party on Sunday
The only thing distinguishing the duo was an unfastened black tie as the couple arrived in matching black suits.
The LA-born actress teamed her look with a black blazer by Saint Laurent, a pair of loose black trousers and black stiletto heels, while Brad opted for the exact same outfit, with just some slight adjustments.
Sporting a Valentino blazer the actor wore a pair of patent brogues to make sure that his look was slightly different.
Talking it out: The actress chatted with the rapper over dinner and drinks
Matching: The duo sported nearly matching tuxedos
Angelina, 38, posed with her handsome 50-year-old husband as Tinie sat between the two wearing a contrasting white tuxedo while they cuddled up in a booth with cocktails at the party.
Earlier in the evening on the red carpet, the pair looked adorable when Angelina was spotted fixing Brad's bow tie to ensure he was well and truly dressed to impress for the most important night in the British film industry's calendar.
Elsewhere, Lupita Nyong'o and Leonardo DiCaprio led the glittering A-list attendees at the 2014 EE BAFTAs at London's Royal Opera House on Sunday night.
Happy lady: The 38-year-old showed off her fabulous figure as she wore her tie undone over a sheer tuxedo shirt
Chummy: The star chatted with a variety of fellow guests at the party
Big names: Rita Ora, Naomi Campbell, Oprah Winfrey and Georgina Chapman were at the Weinstein Co party
Doing them a good turn: And Rita later performed for the gathered dignitaries
Meanwhile, Brangelina recently shared a romantic getaway.
The stars had travelled to Airlie Beach in the Whitsundays while Angelina was filming her new movie Unbroken.
Whilst visiting the small tourist town, Brad and Angelina spent three nights without their six children at Peppers Resort, a waterfront hotel near the town’s centre.
The Peppers resorts and retreats are unique, high-end hotels in some of Australia and New Zealand’s most beautiful locations.
The happy couple were snapped enjoying the view of the ocean from the balcony of their suite, which was one of the three bedroom apartments offered by the resort for between $500 and $800 a night.
Blue beauties: Laura Whitmore and Amy Adams made sure there was plenty of eye candy at the event
Looking Aus-some: Cate Blanchett was close to her peak thanks to this figure-hugging black dress
Outgunned: Jessie J did not quite reach the same heights as model turned designer Georgina Chapman
What's his secret? Beautiful women such as Georgina queue up to pose with multimillionaire movie producer Harvey Weinstein
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